Articles
  • Pressure-assisted combustion synthesis of red-emitting SrIn2O4: Eu3+ phosphor powders for applications in solid state white lamps
  • C.E. Rodríguez-Garcíaa, N. Perea-Lópezb, G.A. Hiratab,c,* and S.P. DenBaarsc
  • a Posgrado en Física de Materiales, CICESE-UNAM. Km 107 Carretera Tijuana-Ensenada. Ensenada, B. C., 22860 México b Centro de Nanociencias y Nanotecnologia -UNAM. Km 107 Carretera Tijuana-Ensenada. Ensenada, B. C., 22860 México c Solid State Lighting and Energy Center, University of California at Santa Barbara, Santa Barbara, CA 93106, U.S.A.
Abstract
Red-emitting phosphor powders of SrIn2O4 activated with Eu3+ ions were synthesized by a high pressure assisted combustion method. X-ray diffraction analysis of the crystalline properties of these powders revealed single phase SrIn2O4 for Eu concentrations up to 4 atomic % of Eu. The photo and cathodoluminescence emission spectra of SrIn2O4: Eu3+ powder shows bright red emission mainly caused by the 5D0→7F2 intra-shell transition of Eu3+. Furthermore, photoluminescence excitation (PLE) spectroscopy revealed that an efficient energy transfer from the SrIn2O4 host lattice onto the Eu ions is accomplished in addition to the excitation band peaked at λ = 396 nm that directly excites the Eu ions, making this material an excellent candidate for applications in solid state white-emitting lamps.

Keywords: Rare Earth, Luminescence, Solid state lamps.

This Article

  • 2008; 9(5): 463-465

    Published on Oct 31, 2008