Articles
  • Preparation of nickel phosphates with various acidic and basic compounds
  • Hiroaki Onodaa,*, Keiichiro Asaia and Atsushi Takenakab
  • a Department of Informatics and Environmental Sciences, Faculty of Life and Environmental Sciences, Kyoto Prefectural University, 1-5, Shimogamo Nakaragi-cyo, Sakyo-ku, Kyoto 606-8522, Japan b Department of Materials Science, Yonago National College of Technology, 4448, Hikona-cho, Yonago, Tottori 683-8502, Japan
Abstract
Malonic acid, propionic acid, glycine, n-butylamine, and urea were added to the preparation of nickel phosphate from nickel nitrate and phosphoric acid solutions. These additives were selected from the viewpoint of the functional groups, in short, both acidic sites, one-sided acidic site, acidic and basic sites, one-sided basic site, and both basic sites. Nickel phosphate was not obtained by the addition of glycine. The Ni/P ratio became larger by the addition of n-butylamine. The effect of the addition of acidic and basic compounds was studied on the chemical composition, powder and functional properties of nickel phosphate materials.

Keywords: Nickel phosphate, Chemical synthesis, Specific surface area, Adsorbent.

This Article

  • 2011; 12(4): 439-442

    Published on Aug 31, 2011