New approach to provide an electrical conductivity to insulator structural ceramics was suggested. In this concept, sintering additives form conductive network after sintering and result in a great reduction of amount of conductive phase addition compared with particle dispersion method generally used. Na+ ionic-conductive silicon nitride and Na+ ionic-conductive magnesia ceramics were successfully fabricated by this method.
Keywords: Critical volume, Glassy Grain boundary phase, Ionic conductivity, Silicon nitride, Magnesia