Suhyun Muna,#, Kyoung Hwa Kimb,#, Seonwoo Parka, Eunmin Kwona, Min Yanga, Hyung Soo Ahna,*, Injun Jeonc, Hunsoo Jeonb, Jae Hak Leea,d, Kwanghee Junge, Won Jae Leee, Myeong-Cheol Shinf and Sang-Mo Koof
aDepartment of Nano-Semiconductor Engineering, National Korea Maritime and Ocean University, Busan 49112, Republic of Korea
bPower Semiconductor Commercialization Center, Busan Techno Park, Busan 46239, Republic of Korea
cDaegu Gyeongbuk Institute of Science & Technology, Division of Energy Technology, Daegu 42988, Republic of Korea
dLNBS Co., Ltd., Busan 48731, Republic of Korea
eDepartment of Advanced Materials Engineering, Dong-Eui University, Busan 47340, Republic of Korea
fDepartment of Electronic Materials Engineering, Kwangwoon University, Seoul 01897, Republic of Korea
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SiC nanostructures are stable without raw material loss even in high-temperature and extreme environments. Thus, they have applications in power semiconductors, optoelectronic devices, and secondary batteries. In this study, SiC nanostructures were grown via the mixed-source hydride vapor-phase epitaxy method with Si and graphite sources, and the growth mechanism was elucidated. The SiC nanostructures primarily grew between the SiC substrate and the graphite source, whereas carbon nanostructures grew on the surface of the graphite source. The properties of the SiC nanostructures grown in this study were characterized using field-emission scanning electron microscopy, energy dispersive spectroscopy, Raman spectroscopy, X-ray diffraction, and high-resolution transmission electron microscopy. The d-spacing between two adjacent lattice fringes was 0.25 nm, which is in good agreement with the interplanar spacing in the (111) or (102) plane directions of SiC. Moreover, the applicability of SiC nanostructures was evaluated by applying the material, which coexists with carbon nanostructures, as an anode in a lithium-ion battery.
Keywords: Mixed-source hydride vapor-phase epitaxy method, SiC nanostructures, Hexagonal SiC, Lithium-ion battery, Raman spectroscopy.
2025; 26(1): 82-90
Published on Feb 28, 2025
Department of Nano-Semiconductor Engineering, National Korea Maritime and Ocean University, Busan 49112, Republic of Korea
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