Articles
  • Mixed alkali effect on the thermal properties of SiO2-B2O3-ZnO-K2O-Na2O glass system
  • Sungmin Son and Seunggu Kang*

  • Department of Advanced Material Engineering, Kyonggi University, Suwon, Kyonggi-do 16227, South Korea

  • This article is an open access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/by-nc/4.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

In this study, we explored the thermal and mechanical properties of a SiO2-B2O3-ZnO-K2O-Na2O (SBZKN) glass composition for potential use in vacuum insulated glass windows. The glass's physical properties were controlled through the mixed alkali effect, with K2O and Na2O serving as network modifiers, maintaining a fixed total of 20%. The SBZKN composition powder vitrified below 1000 °C. Varying the K2O content from 0% to 20% resulted in reduced density and hardness of the glass specimen. DTA analysis indicated decreasing glass transition temperature (Tg) and crystallization temperature (Tp) with higher K2O content, reaching a minimum at 10%. The coefficient of thermal expansion peaked at 10% K2O content, and thermal conductivity was lowest with 15% K2O content. Heating a cube-shaped glass specimen (700 to 800 ℃) caused semicircular spreading due to glass viscosity. Contact angle between spread glass and substrate decreased with temperature but generally increased with K2O content. At 800 ℃, all specimens showed excellent wetting with contact angles of 44° to 72°. This study provides evidence of alkali mixing effects on thermal and mechanical properties, contributing vital data for future vacuum insulated glass window design and development.


Keywords: Vacuum-insulated-glass, Spacer, SBZKN-glass, Mixed-alkali-effect.

This Article

  • 2023; 24(6): 1042-1049

    Published on Dec 31, 2023

  • 10.36410/jcpr.2023.24.6.1042
  • Received on May 24, 2023
  • Revised on Dec 12, 2023
  • Accepted on Dec 12, 2023

Correspondence to

  • Seunggu Kang
  • Department of Advanced Material Engineering, Kyonggi University, Suwon, Kyonggi-do 16227, South Korea
    Tel : +82-31-249-9767 Fax: +82-31-249-9774

  • E-mail: sgkang@kyonggi.ac.kr