Hyeoncheol Kima, T.S. Jeonga,* and T. S. Kimb
aSemiconductor Physics Research Center (SPRC), School of Semiconductor and Chemical Engineering, Jeonbuk National University, Jeonju 54896, Korea
bDepartment of Physics, Jeonbuk National University, Jeonju 54896, Korea
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In this paper, we studied the influence of electric fields on the exciton emissions of the needle-shaped CdS rod by using the combined photocurrent/photoluminescence (PC/PL) spectroscopies. We observed that the exciton emission strongly depended on the electric field while the defect-related emission weakly depended on the electric field. Intensity quenching and peak-shift effects of the exciton spectrum were observed as the electric field increased. To explain these effects, combined PC/PL measurements were introduced and they showed that excitons readily interact with the PC carriers of the photocreated electrons and holes. This interaction reduced the number of carriers participating in recombination, and the cause of the intensity decrease was attributed to the reduced recombination of free excitons. Thus, the shift of the exciton peaks was related to Stark effect induced by electric field. Consequently, we extracted out that exciton–electron scattering in emission spectra were the result of an interaction induced by the external electric field
Keywords: Electric field, Exciton-electron scattering, Stark effect
2022; 23(2): 132-136
Published on Apr 30, 2022
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