Jae-Soo Shin and Seung-Hwan Lee*
Department of Advanced Materials Engineering, Daejeon University, Daejeon 34520, Korea
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In this paper, we successfully synthesized Ti-coated Ni-rich LiNi0.8Co0.1Mn0.1O2 cathode and microstructure and electrochemical performances for high-energy lithium-ion battery are investigated. The TiO2-coated LiNi0.8Co0.1Mn0.1O2 delivers excellent cation mixing and there is no big difference in morphology between pristine and TiO2 coated LiNi0.8Co0.1Mn0.1O2. The TiO2-coated LiNi0.8Co0.1Mn0.1O2 has higher electrochemical performances (initial discharge capacity : 201.3 mAh g-1, rate capability : 90.5% at 4.0 C and cyclability : 79.4% after 100 cycles). It can be explained by the positive role of TiO2 layer on the surface of LiNi0.8Co0.1Mn0.1O2
Keywords: Ti-coated Ni-rich layered LiNi0.8Co0.1Mn0.1O2, microstructure, cation mixing, higher electrochemical performances, TiO2 layer
2021; 22(3): 329-332
Published on Jun 30, 2021
Department of Advanced Materials Engineering, Daejeon University, Daejeon 34520, Korea
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