Jun-Seok Nama, Sang-Min Jeonga, Min-Gyu Choia, Jun-Ho Seoa,* and Shi-Young Yangb,*
aDepartment of Quantum System Engineering, Chonbuk National University, Jeonju 54896, Republic of Korea
bGraduate School of Flexible & Printable Electronics, Chonbuk National University, Jeonju 54896, Republic of Korea
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In this work, in-flight synthesis route of Ga doped ZnO (GZO) nano-powders was investigated experimentally and numerically, using Radio-Frequency (RF) induction plasmas. For experimental study, mixture of micron-sized ZnO and Ga2O3 powders were treated by RF induction plasmas, then, the as-treated powders were retrieved from reactor bottom and filtration for characterization. For numerical study, single particle model was combined with two-dimensional simulation code of RF induction plasma to predict the particle behaviors of ZnO and Ga2O3 depending on their sizes. First, experimental results showed that filtration-retrieved powders were characterized as GZO nano-powders although gallium content can be decreased due to Ga2O3 decomposition into sub-oxides at the elevated temperatures. From reactor bottom, however, spherical structures consisting of Ga2O3 and ZnO particles were observed in sub-millimeter sizes. Numerical results predicted that micron-sized (≤ 10 µm) ZnO and Ga2O3 particles can vaporize easily during the flight of plasma, while particles with the sizes of 25~100 um were simulated to be partially evaporated or unevaporated. Comparing these experimental and numerical results indicates that GZO nano-powders can be synthesized from vapor species of ZnO and Ga2O3, which are primarily produced by in-flight treatment of micron-sized ZnO and Ga2O3 powders in RF induction plasmas
Keywords: Ga doped ZnO, Radio-Frequency induction plasma, Numerical analysis, Nano powder, in-flight heat treatment
2021; 22(2): 169-178
Published on Apr 30, 2021
aDepartment of Quantum System Engineering, Chonbuk National University, Jeonju 54896, Republic of Korea
bGraduate School of Flexible & Printable Electronics, Chonbuk National University, Jeonju 54896, Republic of Korea
Tel: +82-63-270-4295 (Jun-Ho Seo)
Tel: +82-63-270-2022 (Shi-Young Yang)