Vacide Selin Kayaa,b and Mucahit Sutcuc,*
aIzmir Katip Celebi University, The Graduate School
of Natural and Applied Sciences, Izmir 35620, Turkey
bEge University, Aliağa Vocational Training School,
Metallurgy Program, Izmir, Turkey
cIzmir Katip Çelebi University, Faculty of Engineering and
Architecture, Department of Materials Science and Engineering, İzmir 35620,
Turkey
In recent years, the reuse of
industrially generated residues in ceramic bodies has been an important issue.
Reuse of industrial waste products is not only environmental responsibility,
but also cost reduction and efficient use of raw materials. The aim of the
study was to investigate the possibility of using press filter cake (PFC)
instead of calcite in the production of anorthite-based ceramics. The PFC is an
industrial solid waste, which is a by-product in the production of sugar from
sugar beet. This solid waste quantity is about one million ton per year in
Turkey. PFC was evaluated as alternative raw material in the preparation of
anorthite based ceramic bodies. In this study, anorthite based ceramics were
produced by using two different types of calcium oxide source. While PFC and
calcite were used as CaO source, clay was used as the source of aluminum
silicate. Compositions were prepared from 30% calcium oxide sources and 70% clay
by weight. The ceramic bodies were sintered at different temperatures from
1000 oC to 1200 oC. The micro-porous structure
of ceramics were obtained by burning of organic substances and by decomposing
of carbonate compounds of the PFC wastes during firing process. The differences
between the physical, mechanical and microstructural properties of anorthite
based ceramics produced from two different CaO sources were investigated. Also,
their phase analysis results were compared. While the specimens with 30 wt%
PFC addition fired at 1200 oC contained anorthite (CaO·Al2O3·2SiO2)
and cristobalite (SiO2) as major phase, the specimens with 30wt%
calcite addition fired at same temperature included anorthite as major phase
and minor secondary phases such as cristobalite and quartz.
Keywords: Sugar processing wastes, Firing, CAS ceramics, Phase analysis, Microstructure
2020; 21(4): 425-432
Published on Aug 30, 2020
Izmir Katip Çelebi University, Faculty of Engineering and Architecture, Department of Materials Science and Engineering, İzmir 35620, Turkey
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