B. Onwona-Agyemana, N. Lyczkob, D.
P. Minhb, A. Nzihoub and A. Yayaa,*
aDepartment of Materials Science & Engineering, School of Engineering
Sciences, University of Ghana, Legon, Ghana
bUniversité de Toulouse, IMT Mines Albi, RAPSODEE CNRS UMR-5302,
Campus Jarlard, F-81013 Albi cedex 09, France
The aim of this work was to
study five (5) selected local raw clay materials from Ghana using different
characterization techniques such as Thermogravimetric/Differential Thermal
Analysis (TG/DTA), X-ray diffraction (XRD), Fourier Transform Infra-red
Spectroscopy (FTIR), Scanning Electron Microscopy equipped with Energy
Dispersive X-ray Spectroscopy (SEM-EDX) and Nitrogen Desorption (Brunauer-Emmett-Teller, BET) specific surface
area analysis. The clay samples
studied are; Nkroful kaolin (NK), Amanfrom kaolin (AK), Ball clay (BC), Akyem
Feldspar (AF) and Akwatia silica (AS). SEM and EDX show the morphological
features of the five clay samples and also confirm the presence of some
dominant elemental compositions such as aluminium and silicon in all the
samples. FTIR show that the vibrations spectra in the region around 3,600-3,700
cm-1 and 700-800 cm-1 are due to M-OH groups and
that at 900-1000 cm-1 corresponds to Si-O-Si modes.
BET analysis gives specific surface area of the clay samples as NK (4.6 m2/g),
AK (21.9 m2/g), BC (25.50 m2/g), AS (0.79 m2/g)
and AF (0.49 m2/g). X-ray diffraction pattern
confirm the presence of quartz as the major reflection in all the samples
analysed and only kaolinite reflections appeared in three of the samples (NK,
AK and BC). All the kaolinite clays (NK, AK and BC) are suitable starting materials for the fabrication of
electroporcelain insulators, catalytic converters and diesel particulate
filters.
Keywords: Clay, Specific surface area, Electro-porcelain
2020; 21(1): 35-41
Published on Feb 28, 2020
Department of Materials Science & Engineering, School of Engineering Sciences, University of Ghana, Legon, Ghana
Tel : +233559278551