The energy discontinuity in the valence band (Delta E-V) and conduction band (Delta E-C) of (Ce, Tb)MgAl11O19 (CTMA)/InGaZnO4 (IGZO) heterostructure was obtained from X-ray photoelectron spectroscopy measurements. The CTMA exhibited a band gap of similar to 7.02 +/- 0.2 eV from absorption measurements. Determination of the band offsets using Ga 2p(3/2), Zn 2p(3/2) and In 3d(5/2) energy levels as references shows a valence band offset of similar to 0.55 eV. This implies a conduction band offset.E C of similar to 3.27 eV in CTMA/IGZO heterostructures and a nested interface alignment.
Keywords: Band offsets; (Ce,Tb)MgAl11O19/IGZO heterostructure; X-ray photoelectron spectroscopy; Valence band offset