Anisotropic pattern transfer in GaN (undoped and n-type) has been performed by UV photo-enhanced wet etching in KOH, NaOH and AZ400K solutions and a comparison of these electrolytic solutions is presented. The etch mechanism was found to be diffusion-limited (Ea <6 kCal·mol−1) under all conditions whose other characteristics were a square-root dependence of etch rate on time, the production of relatively rough surfaces with a strong dependence of rate on solution agitation, whilst significantly faster etch rates were obtained with bias applied to the sample during light exposure.
Keywords: Photo-enhanced wet etching, GaN, UV illumination, etch mechanism, electrolytic solutions, diffusion-limited.